Experimental assignment of long-range magnetic communication through Pd & Pt metallophilic contacts-Reference-Cited by-同舟云学术

Experimental assignment of long-range magnetic communication through Pd & Pt metallophilic contacts

Published:2023 Issue:2 Volume:14 Page:266-276
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Larsen Emil M. H.¹^ORCID,Bonde Niels A.¹²,Weihe Høgni¹,Ollivier Jacques²,Vosch Tom¹^ORCID,Lohmiller Thomas³⁴^ORCID,Holldack Karsten⁵,Schnegg Alexander⁴⁶,Perfetti Mauro⁷^ORCID,Bendix Jesper¹^ORCID

Affiliation:

1. Department of Chemistry, University of Copenhagen, Universitetsparken 5, DK-2100 Copenhagen, Denmark

2. Institut Laue-Langevin, 71 avenue des Martyrs, CS 20156, 38042 Grenoble Cedex 9, France

3. Humboldt-Universität zu Berlin, Institut für Chemie, Brook-Taylor-Str. 2, 12489 Berlin, Germany

4. EPR4 Energy Joint Lab, Department Spins in Energy Conversion and Quantum Information Science, Helmholtz Zentrum Berlin für Materialien und Energie GmbH, Albert-Einstein-Straße 15, 12489 Berlin, Germany

5. Department of Optics and Beamlines, Helmholtz Zentrum Berlin für Materialien und Energie GmbH, Albert-Einstein-Straße 15, 12489 Berlin, Germany

6. Max Planck Institute for Chemical Energy Conversion, Stiftstrasse 34-36, D-45470 Mülheim an der Ruhr, Germany

7. Department of Chemistry “U. Schiff”, University of Florence, Via della Lastruccia 3-13, Sesto Fiorentino, 50019, Italy

Abstract

The magnetic interaction pathway is experimentally assigned by inelastic neutron scattering in paramagnetic dimers bridged by metallophilic interactions. The magnetic interaction is much stronger via Pt–Pt-bridges than across Pd–Pd-bridges.

Funder

Danmarks Frie Forskningsfond

Deutsche Forschungsgemeinschaft

H2020 European Research Council

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/SC/D2SC05201F

Reference44 articles.

1. Magneto-Structural Properties and Theoretical Studies of a Family of Simple Heterodinuclear Phenoxide/Alkoxide Bridged MnIIILnIII Complexes: On the Nature of the Magnetic Exchange and Magnetic Anisotropy

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3. On the Possibility of Magneto-Structural Correlations: Detailed Studies of Dinickel Carboxylate Complexes

4. Exploiting clock transitions for the chemical design of resilient molecular spin qubits

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