Mechanistic investigation of the aerobic oxidation of 2-pyridylacetate coordinated to a Ru(ii) polypyridyl complex-Reference-Cited by-同舟云学术

Mechanistic investigation of the aerobic oxidation of 2-pyridylacetate coordinated to a Ru(ii) polypyridyl complex

Published:2021 Issue:42 Volume:50 Page:15248-15259
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Sousa Sinval F.¹,Ertem Mehmed Z.²^ORCID,Faustino Leandro A.¹,Machado Antonio Eduardo. H.¹^ORCID,Concepcion Javier J.²^ORCID,Maia Pedro I. S.³^ORCID,Patrocinio Antonio Otavio T.¹^ORCID

Affiliation:

1. Laboratory of Photochemistry and Materials Science, Institute of Chemistry, Universidade Federal de Uberlandia, 38400-902, Uberlandia, Brazil

2. Chemistry Division, Energy & Photon Sciences Directorate, Brookhaven National Laboratory, Upton, USA

3. Núcleo de Desenvolvimento de Compostos Bioativos (NDCBio), Universidade Federal do Triângulo Mineiro, Av. Dr. Randolfo Borges 1400, 38025-440 Uberaba, MG, Brazil

Abstract

A new ruthenium complex with the 2-pyridyl-acetate ligand was synthesized. The coordinated ligand is oxidized by molecular O2 to yield the α-keto-derivative. The reaction mechanism was fully investigated with important implications for catalysis.

Funder

Fundação de Amparo à Pesquisa do Estado de Minas Gerais

Basic Energy Sciences

Conselho Nacional de Desenvolvimento Científico e Tecnológico

Alexander von Humboldt-Stiftung

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/DT/D1DT02461B