The influence of strontium deficiency on thermodynamics of defect formation, structural stability and electrical transport of SrFe0.5Ta0.5O3−δ-based solid solutions with an excess tantalum content

Author:

Politov B. V.12ORCID,Waerenborgh J. C.3ORCID,Shein I. R.1,Merkulov O. V.1ORCID

Affiliation:

1. Institute of Solid State Chemistry, UB RAS, 620990 Ekaterinburg, Russia

2. Institute of Solid State Chemistry and Mechanochemistry, SB RAS, 630128 Novosibirsk, Russia

3. C2TN, Instituto Superior Técnico, Universidade de Lisboa, E.N. 10 ao km 139, 7, 2695-066 Bobadela LRS, Portugal

Abstract

The insertion of Sr vacancy into the crystalline matrix of SrFe0.5−xTa0.5+xO3 oxide materials is shown to influence on thermodynamic, structural, and electrical properties of the resulting compounds.

Funder

Russian Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

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