Protecting-group-directed stereodivergent Tsuji–Trost cyclization: total synthesis of oxylipids and (+)-petromyroxol-Reference-Cited by-同舟云学术

Protecting-group-directed stereodivergent Tsuji–Trost cyclization: total synthesis of oxylipids and (+)-petromyroxol

Published:2023 Issue:14 Volume:59 Page:2007-2010
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Fernandes Rodney A.¹^ORCID,Gorve Dnyaneshwar A.¹,Jha Amit K.¹

Affiliation:

1. Department of Chemistry, Indian Institute of Technology Bombay, Powai, Mumbai 400 076, India

Abstract

A stereodivergent protecting-group-directed Tsuji–Trost cyclization with efficient access to both 2,5-cis- and 2,5-trans-disubstituted-THF scaffolds has been realized with extension to the total synthesis of oxylipids and (+)-petromyroxol.

Funder

Science and Engineering Research Board

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2023/CC/D2CC04579F

Reference33 articles.

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4. Enantioselective homogeneous catalysis involving transition-metal-allyl intermediates

5. Synthesis of 5-Vinyl-2-isoxazolines by Palladium-Catalyzed Intramolecular O-Allylation of Ketoximes

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