Photoredox-catalyzed 1,2-oxo-alkylation of vinyl arenes with 1,3-diketones: an approach to 1,4-dicarbonyls <i>via</i> C

Photoredox-catalyzed 1,2-oxo-alkylation of vinyl arenes with 1,3-diketones: an approach to 1,4-dicarbonyls via C–C activation

Published:2023 Issue:76 Volume:59 Page:11433-11436
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Palani Pushbaraj¹,Arumugam Ajithkumar¹,Raja Dineshkumar¹,Muthu Kesavan²,Senadi Gopal Chandru¹^ORCID

Affiliation:

1. Department of Chemistry, College of Engineering and Technology, SRM Institute of Science and Technology, SRM Nagar, Kattankulathur-603 203, Chengalpattu District, Tamil Nadu, India

2. Interdisciplinary Institute of Indian System of Medicine (IIISM), SRM Institute of Science and Technology, SRM Nagar, Kattankulathur-603 203, Chengalpattu District, Tamil Nadu, India

Abstract

A mild approach to 1,4-diketones in moderate to excellent yields via 1,2-oxo alkylation has been developed using visible-light photocatalysis. The notable feature is the late-stage functionalization of thymol and ibuprofen derivatives.

Funder

Science and Engineering Research Board

SRM Institute of Science and Technology

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2023/CC/D3CC02366D

Reference58 articles.

1. Enterocin, a new antibiotic taxonomy, isolation and characterization.

2. Metalloproteinase Inhibitors, Nonantimicrobial Chemically Modified Tetracyclines, and Ilomastat Block Bacillus anthracis Lethal Factor Activity in Viable Cells

3. Stereodivergent synthesis of 1,4-dicarbonyls by traceless charge–accelerated sulfonium rearrangement

4. Synthese von Pyrrolderivaten

5. Synthese von Thiophen‐ und Pyrrolderivaten

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