Structural, magnetic and spectral properties of tetrahedral cobalt(ii) silanethiolates: a variety of structures and manifestation of field-induced slow magnetic relaxation

Author:

Kowalkowska-Zedler D.12345ORCID,Dołęga A.12345ORCID,Nedelko N.6785ORCID,Łyszczek R.910115ORCID,Aleshkevych P.6785ORCID,Demchenko I.1213145ORCID,Łuczak J.152345ORCID,Ślawska-Waniewska A.6785ORCID,Pladzyk A.12345ORCID

Affiliation:

1. Department of Inorganic Chemistry

2. Faculty of Chemistry

3. Gdańsk University of Technology

4. 80-233 Gdańsk

5. Poland

6. Institute of Physics

7. Polish Academy of Sciences

8. 02-668 Warsaw

9. Department of Coordination and General Chemistry

10. Maria Curie-Skłodowska University

11. 20-031 Lublin

12. Department of Chemistry

13. University of Warsaw

14. 02-093 Warsaw

15. Department of Process Engineering and Chemical Technology

Abstract

Mono-, di- and polynuclear cobalt(ii) silanethiolates in a tetrahedral CoN2S2 environment and a general formula of [Co{SSi(tBuO)3}2(L)2]n have been obtained and their spectroscopic and magnetic properties have been characterized.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Reference75 articles.

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3. The rise of 3-d single-ion magnets in molecular magnetism: towards materials from molecules?

4. S. Tripathi , A.Dey , M.Shanmugam , R. S.Narayanan and V.Chandrsekhar , Cobalt(II) Complexes Single-Ion Magnets , in Topics in Organometallic Chemistry , Springer , Berlin/Heidelberg , 2018

5. Main Group Chemistry at the Interface with Molecular Magnetism

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