Band structure modulation by methoxy-functionalization of graphene nanoribbons

Author:

Götz Alicia123,Wang Xiao-Ye14ORCID,Ruini Alice56ORCID,Zheng Wenhao1,Soltani Paniz1,Graf Robert1ORCID,Tries Alexander1ORCID,Li Juan7,Palma Carlos-Andres7,Molinari Elisa56ORCID,Hansen Michael Ryan8ORCID,Wang Hai I.1ORCID,Prezzi Deborah6ORCID,Müllen Klaus12ORCID,Narita Akimitsu13ORCID

Affiliation:

1. Max Planck Institute for Polymer Research, Ackermannweg 10, D-55128 Mainz, Germany

2. Department of Chemistry, Johannes Gutenberg University Mainz, Duesbergweg 10-14, 55128 Mainz, Germany

3. Organic and Carbon Nanomaterials Unit, Okinawa Institute of Science and Technology Graduate University, 1919-1 Tancha, Onna-son, Okinawa 904-0495, Japan

4. State Key Laboratory of Elemento-Organic Chemistry, College of Chemistry, Nankai University, Tianjin 300071, China

5. Dipartimento di Scienze Fisiche, Informatiche e Matematiche, Università di Modena e Reggio Emilia, 41125 Modena, Italy

6. Istituto Nanoscienze, CNR, via G. Campi 213/a, 41125, Modena, Italy

7. Institute of Physics, Chinese Academy of Sciences, 100190, Beijing, China

8. Institute of Physical Chemistry, Westfälische Wilhelms-Universität Münster, Corrensstr. 28/30, D-48149 Münster, Germany

Abstract

Graphene nanoribbons functionalized with methoxy groups were synthesized. Theoretical studies predicted reduced bandgap and effective mass of charge carriers. THz spectroscopy revealed ∼25% enhancement of the photoconductivity.

Funder

Johannes Gutenberg-Universität Mainz

Deutsche Forschungsgemeinschaft

National Natural Science Foundation of China

Max-Planck-Gesellschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry

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