Oxidation of a triple carbo[5]helicene with hypervalent iodine-Reference-Cited by-同舟云学术

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Oxidation of a triple carbo[5]helicene with hypervalent iodine

Published:2023 Issue:23 Volume:10 Page:5902-5907
ISSN:2052-4129
Container-title:Organic Chemistry Frontiers
language:en
Short-container-title:Org. Chem. Front.

Author:

Rigoulet Florian¹^ORCID,Artigas Albert¹^ORCID,Ferdi Nawal²^ORCID,Giorgi Michel²^ORCID,Coquerel Yoann¹^ORCID

Affiliation:

1. Aix Marseille Université, CNRS, Centrale Marseille, ISM2, 13397 Marseille, France

2. Aix Marseille Université, CNRS, Centrale Marseille, FSCM, 13397 Marseille, France

Abstract

Stereochemistry was found to be a critical factor in the reactivity of the diastereomers of the prototypical triple carbo[5]helicene hexabenzotriphenylene (HBTP): D3-HBTP could be converted into an oxidation rearranged product, but C2-HBTP could not be converted.

Funder

Agence Nationale de la Recherche

Aix-Marseille Université

Centre National de la Recherche Scientifique

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/QO/D3QO01439H

Reference51 articles.

1. Helicenes: Synthesis and Applications

2. One hundred years of helicene chemistry. Part 1: non-stereoselective syntheses of carbohelicenes

3. One hundred years of helicene chemistry. Part 2: stereoselective syntheses and chiral separations of carbohelicenes

4. One hundred years of helicene chemistry. Part 3: applications and properties of carbohelicenes

5. C.-F.Chen and Y.Shen , Helicene chemistry. From synthesis to applications , Springer Berlin , Heidelberg , 2016

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