The effect of solvation in torquoselectivity: ring opening of monosubstituted cyclobutenes-Reference-Cited by-同舟云学术

The effect of solvation in torquoselectivity: ring opening of monosubstituted cyclobutenes

Published:2020 Issue:32 Volume:18 Page:6287-6296
ISSN:1477-0520
Container-title:Organic & Biomolecular Chemistry
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Saadat Kayvan¹²³⁴⁵^ORCID,Villar López Roberto⁶⁷⁸⁹¹⁰^ORCID,Shiri Ali¹²³⁴⁵^ORCID,Nieto Faza Olalla⁶⁷⁸⁹¹⁰^ORCID,Silva López Carlos⁶⁷⁸⁹¹⁰^ORCID

Affiliation:

1. Department of Chemistry

2. Faculty of Science

3. Ferdowsi University of Mashhad

4. Mashhad

5. Iran

6. Departamento de Química Orgánica

7. Universidade de Vigo

8. Campus Lagoas-Marcosende and CITACA

9. Agri-Food Research and Transfer Cluster

10. Campus da Auga

Abstract

The paradigmatic electrocyclic ring opening of monosubstituted cyclobutenes has been used to diagnose possible solvation effects tuning the torquoselectivity observed in these reactions.

Funder

European Regional Development Fund

Ministerio de Ciencia e Innovación

Consellería de Cultura, Educación e Ordenación Universitaria, Xunta de Galicia

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2020/OB/D0OB01229G

Reference58 articles.

1. Stereochemistry of Electrocyclic Reactions

2. The Electronic Mechanism of Electrocyclic Reactions

3. The overlap of two allyl radicals or a four-centered transition state in the cope rearrangement

4. The Conservation of Orbital Symmetry

5. Correlation of Solvolysis Rates and Estimation of Rate Enhancements

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