Characteristic vibrational frequencies of osmium(<scp>ii</scp>) nitrosyl complexes probed by Raman spectroscopy and DFT calculations-Reference-Cited by-同舟云学术

Characteristic vibrational frequencies of osmium(ii) nitrosyl complexes probed by Raman spectroscopy and DFT calculations

Published:2022 Issue:20 Volume:46 Page:9695-9703
ISSN:1144-0546
Container-title:New Journal of Chemistry
language:en
Short-container-title:New J. Chem.

Author:

Bélanger-Desmarais Nicolas¹^ORCID,Gavriluta Anatolie²^ORCID,Tommasino Jean Bernard²^ORCID,Reber Christian¹^ORCID,Luneau Dominique²^ORCID

Affiliation:

1. Département de chimie, Université de Montréal, Montréal, H3C 3J7, Québec, Canada

2. Université Claude Bernard Lyon 1, Laboratoire des Multimatériaux et Interfaces (UMR 5615), Campus de La Doua, 69622, Villeurbanne Cedex, France

Abstract

Raman spectroscopy at variable temperature provides experimental frequencies for osmium(ii) nitrosyl complexes. Vibrational transitions are assigned using DFT calculations.

Funder

Natural Sciences and Engineering Research Council of Canada

Région Auvergne-Rhône-Alpes

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2022/NJ/D2NJ01713J

Reference47 articles.

1. Reduction of the NO+ ligand in the pentacyanonitrosylosmate(II) ion

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3. Not Guilty on Every Count: The “Non‐Innocent” Nitrosyl Ligand in the Framework of IUPAC′s Oxidation‐State Formalism

4. Ruthenium-nitrosyl complexes as NO-releasing molecules, potential anticancer drugs, and photoswitches based on linkage isomerism

5. Structural Influence on the Photochromic Response of a Series of Ruthenium Mononitrosyl Complexes

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