An intermolecular pyrene excimer in the pyrene-labeled N-thiophosphorylated thiourea and its nickel(ii) complex-Reference-Cited by-同舟云学术

An intermolecular pyrene excimer in the pyrene-labeled N-thiophosphorylated thiourea and its nickel(ii) complex

Published:2016 Issue:11 Volume:3 Page:1419-1431
ISSN:2052-1553
Container-title:Inorganic Chemistry Frontiers
language:en
Short-container-title:Inorg. Chem. Front.

Author:

Safin Damir A.¹²³⁴⁵,Babashkina Maria G.¹²³⁴⁵,Mitoraj Mariusz P.⁶⁷⁸⁹¹⁰,Kubisiak Piotr⁶⁷⁸⁹¹⁰,Robeyns Koen¹²³⁴⁵,Bolte Michael¹¹¹²¹³,Garcia Yann¹²³⁴⁵

Affiliation:

1. Institute of Condensed Matter and Nanosciences

2. Molecules

3. Solids and Reactivity (IMCN/MOST)

4. Université catholique de Louvain

5. 1348 Louvain-la-Neuve

6. Department of Theoretical Chemistry

7. Faculty of Chemistry

8. Jagiellonian University

9. 30-060 Cracow

10. Poland

11. Institut für Anorganische Chemie J.-W.-Goethe-Universität

12. Frankfurt/Main

13. Germany

Abstract

(1-pyrene)NHC(S)NHP(S)(OiPr)₂ (HL) and its Ni^II complex ([NiL2]) have been synthesized. Both HL and [NiL2] were found to be emissive in solution of CH₂Cl₂, which is due to the concentration dependent emission of the pyrene monomer and excimer.

Funder

Fédération Wallonie-Bruxelles

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/QI/C6QI00298F

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