Differential capacitance of an electric double layer with asymmetric solvent-mediated interactions: mean-field theory and Monte Carlo simulations

Author:

Caetano Daniel L. Z.12345ORCID,Bossa Guilherme V.1678ORCID,de Oliveira Vinicius M.12345ORCID,Brown Matthew A.910111213ORCID,de Carvalho Sidney J.12345ORCID,May Sylvio1678ORCID

Affiliation:

1. Department of Physics

2. Sao Paulo State University (UNESP)

3. Institute of Biosciences

4. Humanities and Exact Sciences (Ibilce)

5. Brazil

6. North Dakota State University

7. Fargo

8. USA

9. Laboratory for Surface Science and Technology

10. Department of Materials

11. ETH Zürich

12. CH-8093 Zurich

13. Switzerland

Abstract

The differential capacitance of an electrical double layer is directly affected by properties of the electrolyte solution such as temperature, salt concentration, ionic size, and solvent structure.

Funder

São Paulo Research Foundation

Conselho Nacional de Desenvolvimento Científico e Tecnológico

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior

Swiss National Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Reference78 articles.

1. Forces Between Surfaces in Liquids

2. D. F. Evans and H.Wennerström, The colloidal domain, where physics, chemistry, and biology meet, VCH publishers, 2nd edn, 1994

3. Capillary interactions between particles bound to interfaces, liquid films and biomembranes

4. R. J. Hunter , Foundations of colloid science, Oxford University Press, 2001

5. A. G. Volkov , Liquid interfaces in chemical, biological and pharmaceutical applications, CRC Press, 2001

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