Homoleptic hexa- and penta-coordinated gallium(<scp>i</scp>) amide complexes of ruthenium and molybdenum-Reference-Cited by-同舟云学术

Homoleptic hexa- and penta-coordinated gallium(i) amide complexes of ruthenium and molybdenum

Published:2024 Issue: Volume: Page:
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Bühler Raphael¹^ORCID,Weininger Richard J. J.¹^ORCID,Stephan Johannes¹^ORCID,Muhr Maximilian¹,Bock Balasai M.-T.¹,Gemel Christian¹,Fischer Roland A.¹^ORCID

Affiliation:

1. Chair of Inorganic and Metalorganic Chemistry, Technical University of Munich, School of Natural Sciences, Department of Chemistry, Lichtenbergstraße 4, 85748 Garching, Germany and Catalysis Research Center, Erst-Otto-Fischer-Straße 1, 85748 Garching, Germany

Abstract

The all gallium(i)-amide coordinated [Ru(GaTMP)5] and [Mo(GaTMP)6] complexes were isolated and DFT calculations unveil competing π-interaction between the transition metal center and the amido substituent.

Funder

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/DT/D4DT00823E

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3. Synthesis and Characterization of the Novel AlI Compound Al(C5Me4Ph): Comparison of the Coordination Chemistry of Al(C5Me5) and Al(C5Me4Ph) at d10 Metal Centers1)

4. [Pd3(InCp*)4(μ2-InCp*)4]: Three Linearly Arranged Palladium Atoms Wrapped into a Fluxional Shell of Eight InCp* Ligands

5. Quasi-Isomeric Gallium Amides and Imides GaNR2 and RGaNR (R = Organic Group): Reactions of the Digallene, Ar‘GaGaAr‘ (Ar‘ = C6H3-2,6-(C6H3-2,6-Pri2)2) with Unsaturated Nitrogen Compounds