A folded π-system with supramolecularly oriented dipoles: single-component piezoelectric relaxor with NLO activity

Author:

De Soumi1,Asthana Deepak2,Thirmal Chinthakuntla34,Keshri Sudhir K.1,Ghosh Ram Krishna5,Hundal Geeta6ORCID,Kumar Raju7,Singh Satyendra7ORCID,Chatterjee Ratnamala3,Mukhopadhyay Pritam1ORCID

Affiliation:

1. School of Physical Sciences, Jawaharlal Nehru University, New Delhi – 110067, India

2. Department of Chemistry, Ashoka University, Sonipat, Haryana, 131029, India

3. Department of Physics, Indian Institute of Technology Delhi, New Delhi – 110016, India

4. VNR Vignana Jyothi Institute of Engineering and Technology, Hyderabad, Telangana, 500 090, India

5. Department of Electronics & Communications Engineering, Indraprastha Institute of Information Technology, Delhi, New Delhi 110020, India

6. Department of Chemistry, Guru Nanak Dev University, Amritsar, Punjab-143005, India

7. Special Centre for Nanoscience, Jawaharlal Nehru University, New Delhi – 110067, India

Abstract

We have shown that organic folded structures can be utilized to elicit piezo-, ferroelectric and efficient second harmonic generation – all within a single component, macroscopically dipole active system.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

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