Desulfitative Pd-catalysed coupling reaction using benzenesulfonyl chlorides and enones as the coupling partners
Author:
Affiliation:
1. Institut Sciences Chimiques de Rennes
2. UMR 6226 CNRS-Université de Rennes “Organométalliques: Matériaux et Catalyse”
3. Campus de Beaulieu
4. 35042 Rennes
5. France
Abstract
The reaction of benzenesulfonyl chlorides with some enones in the presence of a palladium catalyst affords the conjugate addition products instead of the expected Heck type products.
Publisher
Royal Society of Chemistry (RSC)
Subject
Catalysis
Link
http://pubs.rsc.org/en/content/articlepdf/2015/CY/C5CY00089K
Reference65 articles.
1. M. Oestreich , The Mizoroki–Heck Reaction, Wiley, New York, 2009
2. Intermolecular Dehydrogenative Heck Reactions
3. Pd-Catalyzed Desulfitative Heck Coupling with Dioxygen as the Terminal Oxidant
4. Palladium-Catalyzed Desulfitative Heck-Type Reaction of Aryl Sulfinic Acids with Alkenes
5. Oxidative Mizoroki-Heck-Type Reaction of Arylsulfonyl Hydrazides for a Highly Regio- and Stereoselective Synthesis of Polysubstituted Alkenes
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