Transient intermediate in the formation of an amorphous metal–organic framework-Reference-Cited by-同舟云学术

Transient intermediate in the formation of an amorphous metal–organic framework

Published:2024 Issue:10 Volume:20 Page:2338-2347
ISSN:1744-683X
Container-title:Soft Matter
language:en
Short-container-title:Soft Matter

Author:

Sapnik Adam F.¹^ORCID,Thorne Michael F.¹^ORCID,Castillo-Blas Celia¹,Keenan Luke²^ORCID,Johnson Timothy³^ORCID,Bennett Thomas D.¹^ORCID

Affiliation:

1. Department of Materials Science and Metallurgy, University of Cambridge, Cambridge, CB3 0FS, UK

2. Diamond Light Source Ltd, Diamond House, Harwell Campus, Didcot, Oxfordshire, OX11 0DE, UK

3. Johnson Matthey Technology Centre, Blount's Court, Sonning Common, RG4 9NH, UK

Abstract

Amorphous metal–organic frameworks are rarely formed via direct synthesis. Here, in situ synchrotron X-ray absorption spectroscopy probes the formation of Fe-BTC, revealing a multi-stage mechanism that proceeds via a transient intermediate species.

Funder

Royal Society

Leverhulme Trust

Engineering and Physical Sciences Research Council

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/SM/D3SM01658G

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