Controlling the selectivity of an intramolecular Friedel–Crafts alkylation with alkenes using selenium under mild conditions
Author:
Affiliation:
1. Key Laboratory of Medicinal Chemistry for Natural Resources
2. Ministry of Education and Yunnan Province
3. School of Chemical Science and Technology
4. Yunnan University
5. Kunming
Abstract
An efficiently divergent intramolecular Friedel–Crafts alkylation by unactivated alkenes with seleniranium ion-controlled Markovnikov/anti-Markovnikov specificities under mild conditions has been investigated.
Funder
National Natural Science Foundation of China
Ministry of Education of the People's Republic of China
Yunnan Provincial Science and Technology Department
Yunnan University
Publisher
Royal Society of Chemistry (RSC)
Subject
Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2020/OB/D0OB00257G
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