New palladium(ii) β-ketoesterates for focused electron beam induced deposition: synthesis, structures, and characterization

Author:

Butrymowicz-Kubiak A.1ORCID,Muzioł T. M.1ORCID,Kaczmarek-Kędziera A.1ORCID,Jureddy C. S.2,Maćkosz K.2,Utke I.2ORCID,Szymańska I. B.1ORCID

Affiliation:

1. Faculty of Chemistry, Nicolaus Copernicus University in Toruń, Gagarina 7, 87-100 Toruń, Poland

2. Empa - Swiss Federal Laboratories for Materials Science and Technology, Laboratory for Mechanics of Materials and Nanostructures, Feuerwerkerstrasse 39, CH – 3602 Thun, Switzerland

Abstract

New mononuclear palladium(ii) β-ketoesterates [Pd(CH3COCHCO2R)2] with alkyl substituents R = tBu, iPr, Et can be promising for use in the FEBID. The most volatile and sensitive towards electron irradiation is [Pd(tbaoac)2] existing in the cis form.

Funder

European Cooperation in Science and Technology

Akademia Górniczo-Hutnicza im. Stanislawa Staszica

Uniwersytet Mikolaja Kopernika w Toruniu

Wroclawskie Centrum Sieciowo-Superkomputerowe, Politechnika Wroclawska

Publisher

Royal Society of Chemistry (RSC)

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