Carbon tetrachloride-free allylic halogenation-mediated glycosylations of allyl glycosides-Reference-Cited by-同舟云学术

Carbon tetrachloride-free allylic halogenation-mediated glycosylations of allyl glycosides

Published:2021 Issue:42 Volume:19 Page:9318-9325
ISSN:1477-0520
Container-title:Organic & Biomolecular Chemistry
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Das Anupama¹,Jayaraman Narayanaswamy¹^ORCID

Affiliation:

1. Department of Chemistry, Indian Institute of Science, Bangalore-560012, India

Abstract

A one-pot CCl4-free allylic halide activation of allyl glycosides, followed by glycosylation with acceptors, is conducted in a latent-active manner. PhCF3 as the solvent and TMSOTf/Tf2O as the promoter system are optimal for the reaction.

Funder

Science and Engineering Research Board

Council of Scientific and Industrial Research, India

University Grants Commission

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/OB/D1OB01298C

Reference41 articles.

1. P.Fügedi , Glycosylation Methods , in The Organic Chemistry of Sugars , ed. D. E. Levy and P. Fügedi , CRC Press , Boca Raton, FL , 2006

2. Automated Glycan Assembly: A Perspective

3. HPLC-Assisted Automated Oligosaccharide Synthesis

4. Going to Extremes: “Super” Armed Glycosyl Donors in Glycosylation Chemistry

5. “Active” and “latent” thioglycosyl donors in oligosaccharide synthesis. Application to the synthesis of α-sialosides

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