Development of a novel phosphoramidite-selenide ligand for Pd-catalyzed asymmetric allylic substitution

Author:

Feng Bin12ORCID,Fang Pei-Wen12ORCID,Lan Gui-Man12ORCID,Peng Li-Yan12ORCID,Liang Lu-Fang12ORCID,You Ge-Yun12ORCID

Affiliation:

1. Key Laboratory of Regional Ecological Environment Analysis and Pollution Control in Western Guangxi (Baise University), Education Department of Guangxi Zhuang Autonomous Region, Baise 533000, China

2. College of Chemistry & Environment Engineering, Baise University, Baise 533000, China

Abstract

A novel chiral P,Se-heterodonor ligand has been designed and prepared through an efficient and simple operation. This ligand can be successfully applied to Pd-catalyzed asymmetric allylic substitution with C- and N-nucleophiles.

Funder

National Natural Science Foundation of China

Natural Science Foundation of Guangxi Province

Middle-aged and Young Teachers' Basic Ability Promotion Project of Guangxi

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

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