Spectroscopic and kinetic evidence for redox cycling, catalase and degradation activities of MnIII(TPPS) in a basic aqueous peroxide medium-Reference-Cited by-同舟云学术

Spectroscopic and kinetic evidence for redox cycling, catalase and degradation activities of MnIII(TPPS) in a basic aqueous peroxide medium

Published:2016 Issue:30 Volume:52 Page:5297-5300
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Procner M.¹²³⁴,Orzeł Ł.¹²³⁴,Stochel G.¹²³⁴,van Eldik R.¹²³⁴⁵

Affiliation:

1. Faculty of Chemistry

2. Jagiellonian University

3. 30-066 Kraków

4. Poland

5. Department of Chemistry and Pharmacy

Abstract

Mn^III(TPPS) is oxidized by an excess of hydrogen peroxide in basic aqueous solution to yield Mn^V(TPPS) and/or Mn^IVTPPS, and subsequently reduced back to Mn^III(TPPS) to reveal redox cycling, catalase and degradation activities.

Funder

European Union Agency for Network and Information Security

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2016/CC/C6CC01437B

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