A quest for stable phosphonyl radicals: limitations and possibilities of carbocyclic backbones and bulky substituents-Reference-Cited by-同舟云学术

A quest for stable phosphonyl radicals: limitations and possibilities of carbocyclic backbones and bulky substituents

Published:2023 Issue:39 Volume:52 Page:13930-13945
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Kaymak Pelin¹,Yang Meng¹,Benkő Zoltán¹²^ORCID

Affiliation:

1. Department of Inorganic and Analytical Chemistry, Faculty of Chemical Technology and Biotechnology, Budapest University of Technology and Economics, H-1111 Budapest, Hungary

2. HUN-REN-BME Computation Driven Chemistry Research Group, H-1111 Budapest, Hungary

Abstract

Exploring the electronic and steric stabilisation effects reveals that carbocyclic phosphonyl radicals with remarkably delocalised spin distributions and appropriately selected bulky substituents are suitable for synthetic purposes.

Funder

Budapesti Muszaki és Gazdaságtudományi Egyetem

National Research, Development and Innovation Office

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/DT/D3DT02658B

Reference66 articles.

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2. R. G.Hicks , Stable Radicals: Fundamentals and Applied Aspects of Odd-Electron Compounds , Wiley , 2011

3. AN INSTANCE OF TRIVALENT CARBON: TRIPHENYLMETHYL.

4. Isodiagonality in the periodic table

5. Isolable cyclic (alkyl)(amino)carbene–phosphonyl radical adducts

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