Polymerization of methylsilylenes into polymethylsilanes or polycarbosilanes after dechlorination of dichloromethylsilanes?
Author:
Affiliation:
1. State Key Laboratory of Multi-phase Complex Systems
2. Institute of Process Engineering
3. Chinese Academy of Sciences
4. Beijing
5. China
Abstract
The discovery that dimethylsilylene polymerized into polycarbosilane, not polydimethylsilane, suggests a metallocene catalytic polymerization of 1-silenes as analogues of polyolefins.
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemical Engineering,General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2016/RA/C5RA27889A
Reference25 articles.
1. L. V. Interrante and Q. H.Shen, Silicon-Containing Polymers, ed. R. G. Jones, W. Ando and J. Chojnowski, Kluwer Academic Publishers, Dordrecht, 2000, pp. 247–321
2. Development of a silicon carbide fibre with high tensile strength
3. Development of high tensile strength silicon carbide fibre using an organosilicon polymer precursor
4. Carbosilanes
5. Notes - Thermal Rearrangement of Hexamethyldisilane to Trimethyl(dimethylsilylmethyl)silane
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