Dope it with germanium: selective access to functionalized Si<sub>5</sub>Ge heterocycles-Reference-Cited by-同舟云学术

Dope it with germanium: selective access to functionalized Si₅Ge heterocycles

Published:2023 Issue:6 Volume:59 Page:716-719
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Köstler Benedikt¹^ORCID,Bae Hyunwoo¹,Gilmer Jannik¹,Virovets Alexander¹^ORCID,Lerner Hans-Wolfram¹^ORCID,Albert Philipp²,Fantuzzi Felipe³^ORCID,Wagner Matthias¹^ORCID

Affiliation:

1. Institute for Inorganic and Analytical Chemistry, Goethe University Frankfurt, Max-von-Laue-Straße 7, Frankfurt am Main 60438, Germany

2. Smart Materials, Evonik Operations GmbH, Untere Kanalstraße 3, Rheinfelden 79618, Germany

3. School of Chemistry and Forensic Science, University of Kent, Park Wood Road, Canterbury CT2 7NH, UK

Abstract

The mixed Si5Ge heterocycle (SiCl2)5(GeMe2) and its Cl− diadduct were synthesized in a highly selective fashion. The assembly mechanism was investigated to explain why precisely one GeMe2 group is incorporated, and reactivity studies were performed.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2023/CC/D2CC06060D

Reference37 articles.

1. Effect of Conformation on Electron Localization and Delocalization in Infinite Helical Chains [X(CH3)2]∞ (X = Si, Ge, Sn, and Pb)

2. Polysilane high polymers

3. Singly Bonded Catenated Germanes: Eighty Years of Progress

4. C.Marschner , Oligosilanes in Functional Molecular Silicon Compounds I. Structure and Bonding , ed. D. Scheschkewitz , Springer , Cham , 155 , 2013

5. A luminescent and dichroic hexagermane

Cited by 2 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Regioselective Derivatization of Silylated [20]Silafulleranes;Journal of the American Chemical Society;2023-05-12

2. Group IV heteroadamantanes: synthesis of Si₆Sn₄and site-selective derivatization of Si₆Ge₄;Chemical Communications;2023