High yield and greener C–H difluoromethylation reactions using copper iodide nanoparticles/boron nitride nanosheets as a versatile and recyclable heterogeneous catalyst-Reference-Cited by-同舟云学术

High yield and greener C–H difluoromethylation reactions using copper iodide nanoparticles/boron nitride nanosheets as a versatile and recyclable heterogeneous catalyst

Published:2021 Issue:10 Volume:6 Page:1900-1910
ISSN:2058-9883
Container-title:Reaction Chemistry & Engineering
language:en
Short-container-title:React. Chem. Eng.

Author:

Veerabagu Udayakumar¹²^ORCID,Jaikumar Gowsika³,Lu Fushen²,Quero Franck¹⁴

Affiliation:

1. Laboratorio de Nanocelulosa y Biomateriales, Departamento de Ingeniería Química, Biotecnología y Materiales, Facultad de Ciencias Físicas y Matemáticas, Universidad de Chile, Santiago 8370456, Chile

2. Department of Chemistry and Key Laboratory for Preparation and Application of Ordered Structural Materials of Guangdong Province, Shantou University, Guangdong 515063, China

3. Department of Chemistry, Pachaiyappa's College, University of Madras, Chennai 600030, India

4. Millennium Nucleus on Smart Soft Mechanical Metamaterials, Avenida Beauchef 851, Santiago, 8370456, Chile

Abstract

The 3 wt% CuI/BNNS catalyst exhibited high efficiency for C–H difluoromethylation reactions and enabled greener synthesis at high yields using cyrene as a solvent. Furthermore, the catalyst could be easily recovered and recycled for at least five cycles.

Funder

Fondo Nacional de Desarrollo Científico y Tecnológico

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Fluid Flow and Transfer Processes,Process Chemistry and Technology,Chemical Engineering (miscellaneous),Chemistry (miscellaneous),Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2021/RE/D1RE00196E

Reference45 articles.

1. Introduction of Fluorine and Fluorine-Containing Functional Groups

2. Difluoromethylation Reactions of Organic Compounds