Host-guest chemistry of a bidentate silyl-triflate bis-Lewis acid – complex complexation behaviour unravelled by diffusion NMR spectroscopy-Reference-Cited by-同舟云学术

Host-guest chemistry of a bidentate silyl-triflate bis-Lewis acid – complex complexation behaviour unravelled by diffusion NMR spectroscopy

Published:2022 Issue:18 Volume:51 Page:7164-7173
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Schäfer Fabian¹^ORCID,Mix Andreas¹^ORCID,Cati Ninive¹,Lamm Jan-Hendrik¹^ORCID,Neumann Beate¹,Stammler Hans-Georg¹^ORCID,Mitzel Norbert W.¹^ORCID

Affiliation:

1. Universität Bielefeld, Fakultät für Chemie, Lehrstuhl für Anorganische Chemie und Strukturchemie (ACS), Centre for Molecular Materials (CM2), Universitätsstr. 25, D-33615 Bielefeld, Germany

Abstract

Solution and solid state are markedly different for the adducts of different bipyridines to bidentate silyl-triflate bis-Lewis acids; the solution was studied by diffusion NMR titration experiments and reveals complex aggregates.

Funder

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/DT/D2DT00583B

Reference83 articles.

1. o-Bis(haloorganostannyl)benzenes As Powerful Bidentate Lewis Acids toward Halide Ions

2. An air-stable bisboron complex: a practical bidentate Lewis acid catalyst

3. Syntheses of polyaluminium compounds by hydroalumination reactions, chelating Lewis acids possessing two and four coordinatively unsaturated aluminium atoms