Trifluoroacetic acid molecules confined into/onto metal–organic frameworks using H2btzip for efficiently improving proton conductivity using a synergistic effect

Author:

Ma Xiaoxue1,Li Xin1,Han Xueke1,Zhang Lu1,Liu Ronghua1,Hao Hongguo1ORCID,Yan Hui1,Zhao Xin1,Kong Xiangjin1ORCID,Zhou Huawei1ORCID,Li Xia1ORCID,Zhu Hongjie1,Wang Suna1ORCID,Li Yunwu1ORCID,Zhong Dichang2,Dai Fangna3ORCID

Affiliation:

1. Shandong Provincial Key Laboratory of Chemical Energy Storage and Novel Cell Technology, School of Chemistry and Chemical Engineering, School of Pharmacy, Liaocheng University, Liaocheng 252059, China

2. Institute for New Energy Materials and Low Carbon Technologies School of Materials Science and Engineering Tianjin University of Technology, Tianjin 300384, China

3. College of Science, School of Materials Science and Engineering, China University of Petroleum (East China), Qingdao, Shandong 266580, China

Abstract

Two outstanding proton conducting materials have been obtained by loading TFA molecules onto/into the surface or pores of MOFs. After post-treatment, their proton conductivity values are greatly increased under the same conditions.

Funder

National Natural Science Foundation of China

Natural Science Foundation of Shandong Province

Project of Shandong Province Higher Educational Science and Technology Program

Liaocheng University

Publisher

Royal Society of Chemistry (RSC)

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