A substituent-tolerant synthetic approach to N/P-“loaded” heteroarenes
Author:
Affiliation:
1. Department of Chemistry
2. Indiana University
3. Bloomington
4. USA
5. Nesmeyanov Institute of Organoelement Compounds
Abstract
Tetrazines react with OCP−1 through a reverse electron demand Diels–Alder process to produce 3,6-disubstituted-1,2,4-diazaphosphinin-5-olates.
Funder
National Science Foundation
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2018/DT/C8DT00533H
Reference31 articles.
1. Phosphaalkynes: new building blocks in synthetic chemistry
2. Coulomb repulsion versus cycloaddition: formation of anionic four-membered rings from sodium phosphaethynolate, Na(OCP)
3. Sodium Phosphaethynolate as a Building Block for Heterocycles
4. Iron-Catalyzed [2 + 2 + 2] Cycloaddition Reactions of Diynes with Oxyphosphaethynes To Construct 2-Phosphaphenol Derivatives
5. Inverse electron demand Diels–Alder (iEDDA)-initiated conjugation: a (high) potential click chemistry scheme
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