Electrocatalytic hydrogen production by dinuclear cobalt(ii) compounds containing redox-active diamidate ligands: a combined experimental and theoretical study-Reference-Cited by-同舟云学术

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Electrocatalytic hydrogen production by dinuclear cobalt(ii) compounds containing redox-active diamidate ligands: a combined experimental and theoretical study

Published:2020 Issue:44 Volume:49 Page:15718-15730
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Papanikolaou Michael G.¹²³⁴,Elliott Alexander⁵⁶⁷⁸⁹,McAllister James⁵⁶⁷⁸⁹,Gallos John K.¹⁰¹¹¹²⁴,Keramidas Anastasios D.¹⁰¹³¹⁴¹⁵^ORCID,Kabanos Themistoklis A.¹²³⁴^ORCID,Sproules Stephen⁵⁶⁷⁸⁹^ORCID,Miras Haralampos N.⁵⁶⁷⁸⁹^ORCID

Affiliation:

1. Section of Inorganic and Analytical Chemistry

2. University of Ioannina

3. Ioannina 45110

4. Greece

5. West CHEM

6. School of Chemistry

7. University of Glasgow

8. Glasgow G12 8QQ

9. UK

10. Department of Chemistry

11. Aristotle University of Thessaloniki

12. Thessaloniki GR 541 24

13. University of Cyprus

14. Nicosia 2109

15. Cyprus

Abstract

The chiral dicobalt(ii) complex [Co^II₂(μ₂-L)₂] (1) (H₂L = N²,N⁶-di(quinolin-8-yl)pyridine-2,6-dicarboxamide) and its tert-butyl analogue [Co^II₂(μ₂-LBu)₂] (2) were structurally characterized and their catalytic evolution of H₂ was investigated.

Funder

Hellenic Foundation for Research and Innovation

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2020/DT/D0DT02617D

Reference98 articles.

1. Powering the planet: Chemical challenges in solar energy utilization

2. Low-Cost Hydrogen-Evolution Catalysts Based on Monolayer Platinum on Tungsten Monocarbide Substrates

3. Minimizing the Use of Platinum in Hydrogen-Evolving Electrodes

4. Hydride & dihydrogen complexes of earth abundant metals: structure, reactivity, and applications to catalysis

5. Tuning and mechanistic insights of metal chalcogenide molecular catalysts for the hydrogen-evolution reaction

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4. Exploring the Multifarious Role of the Ligand in Electrocatalytic Hydrogen Evolution Reaction Pathways;Chemistry – A European Journal;2023-11-06

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