Na6Si3S8O: the first example of a sulfide silicate exhibiting unusual tri-polymerized [Si3S8O]6−units without S

Na6Si3S8O: the first example of a sulfide silicate exhibiting unusual tri-polymerized [Si3S8O]6−units without S–O bonds

Published:2017 Issue:39 Volume:46 Page:13356-13359
ISSN:1477-9226
Container-title:Dalton Trans.
language:en
Short-container-title:Dalton Trans.

Author:

Wu Kui¹²³⁴⁵^ORCID,Yang Zhihua¹²³⁴⁵^ORCID,Pan Shilie¹²³⁴⁵^ORCID

Affiliation:

1. Key Laboratory of Functional Materials and Devices for Special Environments of CAS

2. Xinjiang Key Laboratory of Electronic Information Materials and Devices

3. Xinjiang Technical Institute of Physics & Chemistry of CAS

4. Urumqi 830011

5. China

Abstract

A new sulfide silicate – Na₆Si₃S₈O – featuring novel tri-polymerized [Si₃S₈O]⁶⁻units without common S–O bonds has been verified as a promising birefringent material.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2017/DT/C7DT03125D

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