Triclinic La7Zn2P11 with P3−, P24−, and P35− units: a combined study by 31P solid-state NMR spectroscopy and single crystal X-ray diffraction-Reference-Cited by-同舟云学术

Triclinic La₇Zn₂P₁₁ with P³⁻, P₂⁴⁻, and P₃⁵⁻ units: a combined study by ³¹P solid-state NMR spectroscopy and single crystal X-ray diffraction

Published:2024 Issue:15 Volume:53 Page:6720-6730
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Kösters Jutta¹^ORCID,Benndorf Christopher¹²^ORCID,Uesbeck Tobias³^ORCID,Wiegand Thomas⁴⁵^ORCID,Eckert Hellmut³⁶^ORCID,Lincke Hannes¹^ORCID,Pöttgen Rainer¹^ORCID

Affiliation:

1. Institut für Anorganische und Analytische Chemie, Universität Münster, Corrensstraße 30, 48149 Münster, Germany

2. Institut für Anorganische Chemie und Kristallographie, Universität Leipzig, Johannisallee 29, 04103 Leipzig, Germany

3. Institut für Physikalische Chemie, Universität Münster, Corrensstrasse 30, D-48149 Münster, Germany

4. Institut für Technische und Makromolekulare Chemie, RWTH Aachen University, Worringerweg 2, 52074 Aachen, Germany

5. Max-Planck Institut für Chemische Energiekonversion, Stiftstraße 34-36, 45470 Mülheim, Germany

6. Institute of Physics in São Carlos, University of São Paulo, São Carlos, SP 13566-590, Brazil

Abstract

The lanthanum-rich phosphide La7Zn2P11 is an electron precise Zintl phase (7La3+)21+(2Zn2+)4+(4P3−)12−(2P24−)8−(P35−) with isolated P3− phosphide anions, P24− dumb-bells and P35− units.

Funder

Deutsche Forschungsgemeinschaft

Max-Planck-Gesellschaft

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/DT/D4DT00529E

Reference47 articles.

1. Untersuchungen an den Phosphiden und Arseniden des Zinks und Cadmiums. Das Zn3P2-Gitter

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4. Crystal Structure of the ZnP4 Compound

5. The crystal structure of ZnP4