Inducing ring distortions in unsubstituted metallophthalocyanines using axial N-heterocyclic carbenes-Reference-Cited by-同舟云学术

Inducing ring distortions in unsubstituted metallophthalocyanines using axial N-heterocyclic carbenes

Published:2024 Issue:15 Volume:53 Page:6537-6546
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Kidd Steven R.¹,Zhou Wen¹,Warren Jeffrey J.¹^ORCID,Leznoff Daniel B.¹^ORCID

Affiliation:

1. Simon Fraser University, Department of Chemistry, 8888 University Drive, Burnaby BC V5A 1S6, Canada

Abstract

Ring-unsubstituted metallophthalocyanines with N-heterocyclic carbenes are soluble in a variety of solvents. The axial NHC ligands generate ruffle and dome-type distorted Pc-rings, with very prominent deformations in the di-axially substituted PcFeII.

Funder

Natural Sciences and Engineering Research Council of Canada

Natural Resources Canada

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/DT/D4DT00528G

Reference86 articles.

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