A heptanuclear light-harvesting metal-based antenna dendrimer with six Ru(ii)-based chromophores directly powering a single Os(ii)-based energy trap

Author:

La Mazza Emanuele12345,Puntoriero Fausto12345,Nastasi Francesco12345,Laramée-Milette Baptiste6789,Hanan Garry S.6789,Campagna Sebastiano12345ORCID

Affiliation:

1. Dipartimento di Scienze Chimiche

2. Biologiche

3. Farmaceutiche ed Ambientali

4. Università di Messina

5. and Centro di ricerca interuniversitario per la conversione chimica dell'energia solare (SOLAR-CHEM)

6. Département de Chimie

7. Université de Montréal

8. Montréal

9. Canada

Abstract

Quantitative Dexter energy transfer occurs in a novel metal dendrimer 1, from the peripheral Ru(ii) centres to the Os(ii) core, at a rate constant of 9.1 × 1010 s−1.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Reference35 articles.

1. G. R. Newkome , C. N.Moorefield and F.Vögtle, Dendrimers and Dendrons: Concepts, Syntheses, Applications, Wiley-VCH, Weinheim, 2004

2. Designing Dendrimers, ed. S. Campagna, P. Ceroni and F. Puntoriero, John Wiley & Sons, Hoboken, 2012

3. D. A. Tomalia , J. B.Christensen and U.Boas, Dendrimers, Dendrons and Dendritic Polymers, Cambridge University Press, 2012

4. Designing Dendrimers Based on Transition-Metal Complexes. Light-Harvesting Properties and Predetermined Redox Patterns

5. Light-harvesting dendrimers

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