Symmetry-breaking phase transitions, dielectric and magnetic properties of pyrrolidinium-tetrahalidocobaltates

Author:

Ksiądzyna Martyna1,Kinzhybalo Vasyl2,Bieńko Alina1ORCID,Medycki Wojciech3,Jakubas Ryszard1,Rajnák Cyril4ORCID,Boča Roman4ORCID,Ozarowski Andrew5ORCID,Ozerov Mykhaylo5ORCID,Piecha-Bisiorek Anna1ORCID

Affiliation:

1. Faculty of Chemistry, University of Wrocław, F. Joliot-Curie 14, 50-383 Wrocław, Poland

2. Institute of Low Temperature and Structure Research Polish Academy of Sciences, Okólna 2, 50-422 Wrocław, Poland

3. Institute of Molecular Physics, Polish Academy of Sciences, M. Smoluchowskiego 17, 60-179 Poznań, Poland

4. Department of Chemistry, Faculty of Natural Sciences, University of SS Cyril and Methodius, 91701 Trnava, Slovakia

5. National High Magnetic Field Laboratory, Florida State University, 1800 East Paul Dirac Drive, Tallahassee, Florida 32310, USA

Abstract

We report the physicochemical analysis of Co-based pyrrolidinium analogues: (C4H10N)2CoCl4 and (C4H10N)2CoBr4. The results confirm that introducing mobile organic cations into an inorganic network might construct compounds with multiple properties.

Funder

National Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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