A new family of decanuclear Ln7Cr3 clusters exhibiting a magnetocaloric effect-Reference-Cited by-同舟云学术

A new family of decanuclear Ln7Cr3 clusters exhibiting a magnetocaloric effect

Published:2021 Issue:28 Volume:11 Page:17346-17351
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Yin Jia-Jia¹²³⁴⁵,Lu Tian-Qi¹²³⁴⁵,Chen Cheng¹²³⁴⁵,Shi Hai-Yan⁶⁷⁸⁹¹⁰,Zhuang Gui-Lin¹¹¹²¹³¹⁴^ORCID,Zheng Jun¹²³⁴⁵,Fang Xiaolong¹⁵¹⁶⁵¹⁴^ORCID,Zheng Xiu-Ying¹²³⁴⁵^ORCID

Affiliation:

1. Institutes of Physical Science and Information Technology

2. Key Laboratory of Structure and Functional Regulation of Hybrid Materials of Ministry of Education

3. Photoelectric Conversion Energy Materials and Devices Key Laboratory of Anhui Province

4. Anhui University

5. Hefei

6. State Key Laboratory of Physical Chemistry of Solid Surfaces

7. Department of Chemistry

8. College of Chemistry and Chemical Engineering

9. Xiamen University

10. Xiamen

11. College of Chemical Engineering

12. Zhejiang University of Technology

13. Hangzhou

14. China

15. College of Materials and Chemical Engineering

16. Anhui Jianzhu University

Abstract

Two decanuclear Ln–Cr clusters Ln7Cr3 were obtained, which formed a three-dimensional framework with one-dimensional nanopore channel through hydrogen-bond and π-bond interactions. Gd7Cr3 had a magnetic entropy change of 21.1 J kg⁻¹ K⁻¹ at 5 K, 7 T.

Funder

Natural Science Foundation of Anhui Province

National Natural Science Foundation of China

Xiamen University

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/RA/D1RA02734D

Reference60 articles.

1. A Keplerate Magnetic Cluster Featuring an Icosidodecahedron of Ni(II) Ions Encapsulating a Dodecahedron of La(III) Ions