A new echelon of precision polypentenamers: highly isotactic branching on every five carbons

Author:

Brits Stefan1234,Neary William J.1234,Palui Goutam1234,Kennemur Justin G.1234ORCID

Affiliation:

1. Department of Chemistry & Biochemistry

2. Florida State University

3. Tallahassee

4. USA

Abstract

A systematic study shows that bulky allylic substituents on cyclopentene monomers affords a highly precise microstructure after ring-opening metathesis polymerization.

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Polymers and Plastics,Biochemistry,Bioengineering

Reference67 articles.

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2. P. C. Hiemenz and T.Lodge , Polymer Chemistry , CRC Press , Boca Raton , 2nd edn, 2007

3. G. G. Odian , Principles of polymerization , Wiley-Interscience , Hoboken, N.J. , 4th edn, 2004

4. Living alkene polymerization: New methods for the precision synthesis of polyolefins

5. Development of Group IV Molecular Catalysts for High Temperature Ethylene-α-Olefin Copolymerization Reactions

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