Exploring the role of polymer hydrophobicity in polymer–metal binding thermodynamics-Reference-Cited by-同舟云学术

Exploring the role of polymer hydrophobicity in polymer–metal binding thermodynamics

Published:2022 Issue:6 Volume:24 Page:3579-3585
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Archer William R.¹^ORCID,Gallagher Connor M. B.¹^ORCID,Vaissier Welborn V.¹^ORCID,Schulz Michael D.¹^ORCID

Affiliation:

1. Department of Chemistry, Macromolecules Innovation Institute (MII), Virginia Tech, Blacksburg, VA 24060, USA

Abstract

We used isothermal titration calorimetry and atomistic simulations to probe polymer–metal–water interactions in rare-earth element chelation. Varying polymer hydrophobicity produced large changes in heat capacity, driven by changes in desolvation.

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2022/CP/D1CP05263B

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