Palladium catalyzed remote-<i>meta</i>-C–H functionalization of aniline scaffolds-Reference-Cited by-同舟云学术

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Palladium catalyzed remote-meta-C–H functionalization of aniline scaffolds

Published:2024 Issue:5 Volume:11 Page:1473-1478
ISSN:2052-4129
Container-title:Organic Chemistry Frontiers
language:en
Short-container-title:Org. Chem. Front.

Author:

Srinivas Dasari¹,Satyanarayana Gedu¹^ORCID

Affiliation:

1. Department of Chemistry, Indian Institute of Technology (IIT), Hyderabad, Kandi, Sangareddy – 502284, India

Abstract

Here, we report on a microwave-assisted accelerated meta-C–H olefination of aniline derivatives using a simple aliphatic end-on nitrile assembly. Notably, the protocol shows broad substrate compatibility with remarkable regio-selectivity.

Funder

Department of Science and Technology, Ministry of Science and Technology

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/QO/D3QO01943H

Reference53 articles.

1. C–H bond activation enables the rapid construction and late-stage diversification of functional molecules

2. 2-(Pyridin-2-yl)isopropyl (PIP) Amine: An Enabling Directing Group for Divergent and Asymmetric Functionalization of Unactivated Methylene C(sp3)–H Bonds

3. Transition-Metal-Catalyzed, Coordination-Assisted Functionalization of Nonactivated C(sp3)–H Bonds

4. Coordination-assisted, transition-metal-catalyzed enantioselective desymmetric C–H functionalization

5. The ortho effect in directed C–H activation

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