Diverse mixtures of 2,4-dihydroxy tautomers and O4 protonated conformers of uridine and 2′-deoxyuridine coexist in the gas phase
Author:
Affiliation:
1. Department of Chemistry
2. Wayne State University
3. Detroit
4. USA
5. Radboud University Nijmegen
6. Institute for Molecules and Materials
7. FELIX Facility
8. Nijmegen
9. The Netherlands
Abstract
IRMPD spectroscopy and theoretical studies reveal that a diverse mixture of minor 2,4-dihydroxy and O4 protonated tautomeric conformations of the protonated forms of uridine and 2′-deoxyuridine are populated by ESI.
Funder
Office of International and Integrative Activities
Division of Chemistry
Publisher
Royal Society of Chemistry (RSC)
Subject
Physical and Theoretical Chemistry,General Physics and Astronomy
Link
http://pubs.rsc.org/en/content/articlepdf/2015/CP/C5CP02227D
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4. G. A. Jeffrey and W.Saenger, Hydrogen Bonding in Biological Structure, Springer-Verlag, New York, 1991
5. The molecular structures of nucleosides and nucleotides
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