BP double bonds relieved from steric encumbrance: matrix-isolation infrared spectroscopy of the phosphaborene F<sub>2</sub>B–PBF and the triradical BPF<sub>3</sub>-Reference-Cited by-同舟云学术

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BP double bonds relieved from steric encumbrance: matrix-isolation infrared spectroscopy of the phosphaborene F₂B–PBF and the triradical BPF₃

Published:2024 Issue:21 Volume:15 Page:8045-8051
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Wen Mei¹^ORCID,Medel Robert¹^ORCID,Zasimov Pavel V.¹^ORCID,Müller Carsten¹^ORCID,Riedel Sebastian¹^ORCID

Affiliation:

1. Freie Universität Berlin, Institut für Chemie und Biochemie – Anorganische Chemie, Fabeckstraße 34/36, 14195 Berlin, Germany

Abstract

The BPF3 triradical adduct is obtained by the reaction of laser-ablated boron atoms with PF3 in a solid neon matrix. Additionally, the phosphaborene F2B–PBF without sterically demanding ligands but with an acute BPB angle is observed.

Funder

H2020 European Research Council

Deutsche Forschungsgemeinschaft

China Scholarship Council

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/SC/D4SC01913J

Reference32 articles.

1. Recent Advances in the Chemistry of Iminoborane Derivatives

2. On the structure of HBPH

3. Triple-Bonded Boron≡Phosphorus Molecule: Is That Possible?

4. Production of a boraphosphene (RB:PR') in the vapor phase by thermolysis of a sterically encumbered diphosphadiboretane

5. An Allene-analogous Boranylidenephosphane with BP Double Bond: 1,1-Diethylpropyl(2,2,6,6-tetramethylpiperidino)-boranylidenephosphane-P-pentacarbonylchromium

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