Highly active, chemo- and enantioselective Pt-SPO catalytic systems for the synthesis of aromatic carboxamides

Author:

Gulyás Henrik123,Rivilla Ivan4567,Curreli Simona89107,Freixa Zoraida111213147,van Leeuwen Piet W. N. M.89107

Affiliation:

1. XiMo Hungary Ltd.

2. Budapest

3. Hungary

4. Department of Organic Chemistry I

5. University of the Basque Country (UPV/EHU), and Donostia International Physics Center (DIPC)

6. San Sebastián – Donostia

7. Spain

8. Institute of Chemical Research of Catalonia (ICIQ)

9. Avda Països Catalans 16

10. Tarragona

11. Department of Applied Chemistry

12. Faculty of Chemistry

13. University of the Basque Country (UPV-EHU)

14. San Sebastián

Abstract

Platinum complexes of the chiral non-racemizing SPO ligand 1 have been discovered to be the first artificial transition metal complexes providing kinetic resolution in the hydration of a racemic chiral nitrile.

Funder

Ministerio de Ciencia e Innovación

Publisher

Royal Society of Chemistry (RSC)

Subject

Catalysis

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