Fe(ii) and Fe(iii) dithiocarbamate complexes as single source precursors to nanoscale iron sulfides: a combined synthetic and in situ XAS approach

Author:

Roffey Anna12341ORCID,Hollingsworth Nathan1564,Islam Husn-Ubayda15647,Bras Wim7891011ORCID,Sankar Gopinathan1564,de Leeuw Nora H.1213144ORCID,Hogarth Graeme1234ORCID

Affiliation:

1. Department of Chemistry

2. King's College London

3. London SE1 1DB

4. UK

5. University College London

6. London WC1H OAJ

7. Netherlands Organisation for Scientific Research DUBBLE@ESRF

8. 38043 Grenoble

9. France

10. Chemistry Division

11. Oak Ridge National Laboratory

12. School of Chemistry

13. Cardiff University

14. Cardiff

Abstract

Fe(ii) and Fe(iii) dithiocarbamates are precursors to a range of nanoparticulate iron sulfides and in situ studies give insight into the molecular decomposition mechanism being dominated by reductive-elimination of thiuram disulfide and amide-exchange.

Funder

Engineering and Physical Sciences Research Council

Oak Ridge National Laboratory

Publisher

Royal Society of Chemistry (RSC)

Subject

General Engineering,General Materials Science,General Chemistry,Atomic and Molecular Physics, and Optics,Bioengineering

同舟云学术

1.学者识别学者识别

2.学术分析学术分析

3.人才评估人才评估

"同舟云学术"是以全球学者为主线,采集、加工和组织学术论文而形成的新型学术文献查询和分析系统,可以对全球学者进行文献检索和人才价值评估。用户可以通过关注某些学科领域的顶尖人物而持续追踪该领域的学科进展和研究前沿。经过近期的数据扩容,当前同舟云学术共收录了国内外主流学术期刊6万余种,收集的期刊论文及会议论文总量共计约1.5亿篇,并以每天添加12000余篇中外论文的速度递增。我们也可以为用户提供个性化、定制化的学者数据。欢迎来电咨询!咨询电话:010-8811{复制后删除}0370

www.globalauthorid.com

TOP

Copyright © 2019-2024 北京同舟云网络信息技术有限公司
京公网安备11010802033243号  京ICP备18003416号-3