Fe(ii) and Fe(iii) dithiocarbamate complexes as single source precursors to nanoscale iron sulfides: a combined synthetic and in situ XAS approach-Reference-Cited by-同舟云学术

Fe(ii) and Fe(iii) dithiocarbamate complexes as single source precursors to nanoscale iron sulfides: a combined synthetic and in situ XAS approach

Published:2019 Issue:8 Volume:1 Page:2965-2978
ISSN:2516-0230
Container-title:Nanoscale Advances
language:en
Short-container-title:Nanoscale Adv.

Author:

Roffey Anna¹²³⁴¹^ORCID,Hollingsworth Nathan¹⁵⁶⁴,Islam Husn-Ubayda¹⁵⁶⁴⁷,Bras Wim⁷⁸⁹¹⁰¹¹^ORCID,Sankar Gopinathan¹⁵⁶⁴,de Leeuw Nora H.¹²¹³¹⁴⁴^ORCID,Hogarth Graeme¹²³⁴^ORCID

Affiliation:

1. Department of Chemistry

2. King's College London

3. London SE1 1DB

4. UK

5. University College London

6. London WC1H OAJ

7. Netherlands Organisation for Scientific Research DUBBLE@ESRF

8. 38043 Grenoble

9. France

10. Chemistry Division

11. Oak Ridge National Laboratory

12. School of Chemistry

13. Cardiff University

14. Cardiff

Abstract

Fe(ii) and Fe(iii) dithiocarbamates are precursors to a range of nanoparticulate iron sulfides and in situ studies give insight into the molecular decomposition mechanism being dominated by reductive-elimination of thiuram disulfide and amide-exchange.

Funder

Engineering and Physical Sciences Research Council

Oak Ridge National Laboratory

Publisher

Royal Society of Chemistry (RSC)

Subject

General Engineering,General Materials Science,General Chemistry,Atomic and Molecular Physics, and Optics,Bioengineering

Link

http://pubs.rsc.org/en/content/articlepdf/2019/NA/C9NA00262F

Reference79 articles.

1. Chemistry of Iron Sulfides

2. Bioinspired Iron Sulfide Nanoparticles for Cheap and Long-Lived Electrocatalytic Molecular Hydrogen Evolution in Neutral Water