The ubiquitous cross-coupling catalyst system ‘Pd(OAc)2’/2PPh3 forms a unique dinuclear PdI complex: an important entry point into catalytically competent cyclic Pd3 clusters
Author:
Affiliation:
1. Department of Chemistry
2. University of York
3. York
4. UK
5. Bayer Aktiengesellschaft
6. Crop Science Division
7. 65926 Frankfurt am Main
8. Germany
9. Bayer AG
10. 41539 Dormagen
Abstract
Pd3-type clusters generated from Pd(OAc)2/nPPh3, formed via a dinuclear Pd(i) species, exhibit high activity in Suzuki–Miyaura cross-coupling.
Funder
Bayer
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2019/SC/C9SC01847F
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