Overall reaction mechanism of photocatalytic CO2 reduction on a Re(i)-complex catalyst unit of a Ru(ii)–Re(i) supramolecular photocatalyst

Author:

Kamogawa Kei1ORCID,Kato Yuki2,Tamaki Yusuke1ORCID,Noguchi Takumi2ORCID,Nozaki Koichi3ORCID,Nakagawa Tatsuo4,Ishitani Osamu15ORCID

Affiliation:

1. Department of Chemistry, School of Science, Tokyo Institute of Technology, 2-12-1-NE-2 O-okayama, Meguro-ku, Tokyo 152-8550, Japan

2. Department of Physics, Graduate School of Science, Nagoya University, Nagoya 464-8602, Japan

3. Department of Chemistry, Graduated School of Science and Engineering, University of Toyama, 3190, Gofuku, Toya-ma-shi, Toyama 930-8555, Japan

4. UNISOKU Co., Ltd, 2-4-3 Kasugano, Hirakata, Osaka, 573-0131, Japan

5. Department of Chemistry, Graduate School of Advanced Science and Engineering, Hiroshima University, 1-3-1 Kagamiyama, Higashi-Hiroshima, Hiroshima 739 8526, Japan

Abstract

The whole mechanism of photocatalytic CO2 reduction to CO by a Ru(ii)–Re(i) supramolecular photocatalyst was successfully clarified using time-resolved infrared spectroscopy, UHPLC analysis, electrochemical measurements, and DFT calculations.

Funder

Japan Society for the Promotion of Science

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

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