Tunable reactivity of geminal bis(silyl) enol derivatives leading to selective exo-IEDDA or Sakurai allylation with a β,γ-unsaturated ketoester-Reference-Cited by-同舟云学术

Tunable reactivity of geminal bis(silyl) enol derivatives leading to selective exo-IEDDA or Sakurai allylation with a β,γ-unsaturated ketoester

Published:2016 Issue:66 Volume:52 Page:10137-10140
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Gan Zubao¹²³⁴⁵,Chu Zhiwen¹²³⁴⁵,Hu Jia¹²³⁴⁵,Su Zhishan⁶⁷⁸³⁴,Hu Changwei⁶⁷⁸³⁴,Gao Lu¹²³⁴⁵,Song Zhenlei¹²³⁴⁵

Affiliation:

1. Key Laboratory of Drug-Targeting and Drug Delivery System of the Education Ministry

2. West China School of Pharmacy

3. Sichuan University

4. Chengdu

5. China

6. Key Laboratory of Green Chemistry and Technology

7. Ministry of Education

8. College of Chemistry

Abstract

Two contrasting pathways in a SnCl₄-catalyzed reaction of geminal bis(silyl) enol derivatives with β,γ-unsaturated ketoesters have been achieved by tuning the R group in the enol moiety.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2016/CC/C6CC04593F

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