Rhodium-catalyzed C–H functionalization-based approach to eight-membered lactams-Reference-Cited by-同舟云学术

Rhodium-catalyzed C–H functionalization-based approach to eight-membered lactams

Published:2015 Issue:4 Volume:6 Page:2275-2285
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Wu Shangze¹²³⁴⁵,Zeng Rong¹²³⁴⁵,Fu Chunling¹²³⁴⁵,Yu Yihua⁶⁷⁸⁹⁵,Zhang Xue¹⁰¹¹¹²⁵,Ma Shengming¹²³⁴⁵

Affiliation:

1. Laboratory of Molecular Recognition and Synthesis

2. Department of Chemistry

3. Zhejiang University

4. Hangzhou 310027

5. P. R. China

6. Shanghai Key Laboratory of Magnetic Resonance

7. Department of Physics

8. East China Normal University

9. Shanghai 200062

10. State Key Laboratory of Organometallic Chemistry Shanghai Institute of Organic Chemistry

11. Chinese Academy of Sciences

12. Shanghai 200032

Abstract

Fused tricyclic skeleton in one shot: a Rh^III catalyzed formal [4 + 2 + 2] cyclization of N-pivaloyloxybenzamides 1 with 1,6-allene-enes 2 adding two cycles to the benzene ring compatible with ambient air and moisture with a tolerance of many synthetic useful functional groups at room temperature have been developed.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/SC/C5SC00092K

Reference134 articles.

1. Total Synthesis of Natural 8- and 9-Membered Lactones: Recent Advancements in Medium-Sized Ring Formation

2. Ring closure reactions of bifunctional chain molecules

3. The structure elucidation of three tetrahydroquinolylimidazole alkaloids from Macrorungia longistrobus C.B.Cl. (acanthaceae)

4. Sulpinines A-C and secopenitrem B: new antiinsectan metabolites from the sclerotia of Aspergillus sulphureus

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