Evidence for ultrafast formation of tribenzoylgermyl radicals originating from tetraacylgermane photoinitiators-Reference-Cited by-同舟云学术

Evidence for ultrafast formation of tribenzoylgermyl radicals originating from tetraacylgermane photoinitiators

Published:2020 Issue:24 Volume:11 Page:3972-3979
ISSN:1759-9954
Container-title:Polymer Chemistry
language:en
Short-container-title:Polym. Chem.

Author:

Jöckle Philipp¹²³⁴⁵,Lamparth Iris⁶⁷⁸,Moszner Norbert⁶⁷⁸,Barner-Kowollik Christopher⁹¹⁰¹¹¹²¹³^ORCID,Unterreiner Andreas-Neil¹²³⁴⁵^ORCID

Affiliation:

1. Molekulare Physikalische Chemie

2. Institut für Physikalische Chemie

3. Karlsruhe Institute of Technology (KIT)

4. 76131 Karlsruhe

5. Germany

6. Ivoclar Vivadent AG

7. 9494 Schaan

8. Liechtenstein

9. Centre for Materials Science

10. School of Chemistry and Physics

11. Queensland University of Technology (QUT)

12. Brisbane

13. Australia

Abstract

We report strong evidence for the ultrafast formation of tribenzoylgermyl radicals originating from tetraacylgermane photoinitiators on a ps-time scale. In comparison to previous studies, the result can be related to a high initiation efficiency.

Funder

Australian Research Council

Queensland University of Technology

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Polymers and Plastics,Biochemistry,Bioengineering

Link

http://pubs.rsc.org/en/content/articlepdf/2020/PY/D0PY00344A

Reference39 articles.

1. A review of trends and limitations in hydrogel-rapid prototyping for tissue engineering

2. Photopolymerizable hydrogels for tissue engineering applications

3. The Materials Challenge in Diffraction-Unlimited Direct-Laser-Writing Optical Lithography

4. Advancements in photoinitiators—Opening up new applications for radiation curing

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