93% single-atom utilization in base-resistant metal–organic framework quantum dots for ampere-level CO2 electroreduction

Author:

Ni Wenpeng1,He Xiaodong2ORCID,Chen Houjun1,Dai Minyang1,Zhang Wei1,Zhang Yan1ORCID,Wang Shuangyin3ORCID,Zhang Shiguo1ORCID

Affiliation:

1. College of Materials Science and Engineering, Hunan University, Changsha 410082, China

2. Institute of Optoelectronics and Electromagnetic Information, School of Information Science and Engineering, Lanzhou University, Lanzhou, 730000, China

3. State Key Laboratory of Chem/Bio-Sensing and Chemometrics, Advanced Catalytic Engineering Research Center of the Ministry of Education, College of Chemistry and Chemical Engineering, Hunan University, Changsha 410082, China

Abstract

A single-atom utilization of 93% is realized by downsizing MOF particles into quantum dots featuring a shorter diffusion path and a stronger substrate–MOF electronic interaction, thus promoting mass and interfacial electron transfer.

Funder

National Natural Science Foundation of China

Natural Science Foundation of Hunan Province

National Key Research and Development Program of China

Publisher

Royal Society of Chemistry (RSC)

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