Nanometric distance measurements between Mn(ii)DOTA centers

Author:

Vincent Ching H. Y.12345,Demay-Drouhard Paul678910,Bertrand Hélène C.678910,Policar Clotilde678910,Tabares Leandro C.12345,Un Sun12345

Affiliation:

1. Institute for Integrative Biology of the Cell (I2BC)

2. Department of Biochemistry

3. Biophysics and Structural Biology

4. Université Paris-Saclay

5. CEA

6. Ecole Normale Supérieure-PSL Research University

7. Départment de Chimie

8. Sorbonne Universités – UPMC Univ Paris 06

9. CNRS UMR 7203 LBM

10. F-75005 Paris

Abstract

The distance between two Mn(ii)DOTA complexes attached to the ends of polyproline helices of varying lengths was measured by 94 GHz PELDOR spectroscopy with good accuracy demonstrating their effectiveness as spin-labels.

Funder

Institut National des Sciences de l'Univers, Centre National de la Recherche Scientifique

Agence Nationale de la Recherche

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

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