Oxidation-induced ambiphilicity triggers N–N bond formation and dinitrogen release in octahedral terminal molybdenum(<scp>v</scp>) nitrido complexes-Reference-Cited by-同舟云学术

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Oxidation-induced ambiphilicity triggers N–N bond formation and dinitrogen release in octahedral terminal molybdenum(v) nitrido complexes

Published:2024 Issue:14 Volume:15 Page:5152-5162
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Almquist C. Christopher¹^ORCID,Rajeshkumar Thayalan²,Jayaweera H. D. A. Chathumal¹,Removski Nicole¹,Zhou Wen¹,Gelfand Benjamin S.¹,Maron Laurent²,Piers Warren E.¹^ORCID

Affiliation:

1. Department of Chemistry, University of Calgary, 2500 University Drive NW, Calgary, Alberta, T2N 1N4, Canada

2. LPCNO, Université de Toulouse, INSA, UPS, Toulouse, France

Abstract

N–N bond formation in octahedral, terminal d1 Mo(v) nitridos to give μ-dinitrogen complexes requires one eletron oxidation with 0.5 equivalents of oxidant to open a kinetically feasible ambiphilic nitrido coupling pathway.

Funder

Natural Sciences and Engineering Research Council of Canada

Alberta Innovates

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/SC/D4SC00090K

Reference72 articles.

1. Beyond fossil fuel–driven nitrogen transformations

2. Oxidation of coordinated ammonia to nitrate

3. Homogeneous electrocatalytic oxidation of ammonia to N2 under mild conditions

4. Ruthenium-catalysed oxidative conversion of ammonia into dinitrogen

5. Catalytic Ammonia Oxidation to Dinitrogen by Hydrogen Atom Abstraction

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